Azido[1,2-bis(diphenylphosphanyl)ethane-κ2 P,P′](η5-indenyl)ruthenium(II)
نویسندگان
چکیده
Facile ligand substitution is observed when the ruthenium chloride complex [Ru(η(5)-C(9)H(7))Cl(dppe)] (dppe is diphenylphosphanyl ethane) is treated with NaN(3) in refluxing ethanol, yielding the title compound, [Ru(η(5)-C(9)H(7))(N(3))(dppe)] or [Ru(C(9)H(7))(N(3))(C(26)H(24)P(2))]. The Ru(II) atom has a typical piano-stool coordination. The Ru-P bond lengths are 2.284 (2) and 2.235 (2) Å. NMR and MS analyses are in agreement with the structure of the title compound.
منابع مشابه
[1,4-Bis(diphenylphosphanyl)butane-κ2 P,P′]chlorido(η5-indenyl)ruthenium(II)
Facile ligand substitution is observed when the ruthenium chloride complex [Ru(η(5)-C(9)H(7))Cl(PPh(3))(2)] is treated with 1,4-bis-(diphenyl-phosphan-yl)butane in refluxing toluene yielding the title compound, [Ru(C(9)H(7))Cl(C(28)H(28)P(2))]. The Ru(II) atom has a typical piano-stool coordination, defined by the indenyl ligand, one Cl atom and two phosphanyl P atoms. The Ru-P bond lengths are...
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